Mercapto-methylimidazole Molecular Memristors for High-Performance Resistive Switching and Artificial Synaptic Emulation

🔗 원문 전체 보기 → Royal Society of Chemistry

요약

Nanoscale, 2026, Accepted ManuscriptDOI: 10.1039/D6NR00930A, PaperKrishnendu Karmakar, Mubashir Mushtaq Ganaie, Arindam Biswas, Atanu Betal, Mahesh Kumar, Arup K Rath, Satyajit SahuOrganic molecule based memristive devices are promising candidate for nextgene…

본문

Mercapto-methylimidazole Molecular Memristors for High-Performance Resistive Switching and Artificial Synaptic Emulation

Abstract

Organic molecule based memristive devices are promising candidate for nextgeneration data storage devices for their scalability and low cost. This work discusses resistive memory device based on small organic molecule 2-Mercapto-1-methylimidazole (MMI) and the polymer poly 4-vinylpyridine (PVP), which exhibits stable resistive switching with high on-off ratio (5.48×10 3 ), retention over 3.6×10 4 sec and endurance over 700 cycles. In addition to memory behavior, the MMI organic molecule-based memristor exhibits synaptic functions crucial for neuromorphic computing. The device shows analog modulation of conductance in accordance with voltage pulse protocols, which mimic essential biological learning mechanisms, including potentiation, depression, short-term plasticity (STP), long-term plasticity (LTP), and paired-pulse facilitation (PPF). The device also demonstrates associative learning via Pavlovian conditioning, demonstrating its potential as a hardware-implemented artificial synapse in emerging braininspired systems. The carrier transport in these devices follows multiple conduction mechanisms, including direct tunneling, trap-free and trap-assisted space-charge limited conduction (SCLC), and Ohmic conduction. The switching is attributed to metallic filament formation from top electrode which is further supported by impedance measurements. This study highlights potential of molecular memristors for next generation memory and neuromorphic computing.